中国碘的层与层之间弱的范德华力提供了将体相碘分离为少层纳米片的机会。

首条（图17）图17 ZnHCF@MnO2作为水系锌离子电池正极。电气（图3）图3 典型碱金属离子嵌入机制。

TEM验证了CoNi-HCF表面约15nm左右的NiHCF包覆层，范线该包覆层有效降低充放电循环过程中的晶格紊乱，并抑制副反应，因此获得优异的循环稳定性。建成（a）Zn2+在CoHCF框架结构中可逆嵌入/脱出。中国Kim,Jaekook,ElectrochemicallyInducedStructuralTransformationinaγ-MnO2CathodeofaHighCapacityZinc-IonBatterySystem.ChemistryofMaterials2015,27 (10), 3609−3620.[7]YangLiu,Y.Q.,WuxingZhang,ZhenLi,XiaoJi,LingMiao,LixiaYuan,XianluoHu,YunhuiHuang,SodiumstorageinNa-richNaxFeFe(CN)6nanocubes.NanoEnergy2015,12,386–393.[8]DaweiSu,A.M.,Shi-ZhangQiao,GuoxiuWang,High-CapacityAqueousPotassium-IonBatteriesforLarge-ScaleEnergyStorage.Adv. Mater.2017,29,1604007.[9]JinpengWu,J.S.,KehuaDai,ZengqingZhuo,L.AndrewWray,GaoLiu,Zhi-xunShen,RongZeng,YuhaoLu,WanliYang,ModificationofTransition-MetalRedoxbyInterstitialWaterinHexacyanometalateElectrodesforSodium-IonBatteries.J. Am.Chem.Soc.2017,139,18358−18364.[10]WeijieLi,C.H.,WanlinWang,QingbingXia,ShuleiChou,QinfenGu,BerntJohannessen,HuaKunLiu,andShixueDou,StressDistortionRestrainttoBoosttheSodiumIonStoragePerformanceofaNovelBinaryHexacyanoferrate.Adv.EnergyMater.2019,1903006.[11]PuHu,W.P.,BoWang,DongdongXiao,UtkarshAhuja,JulienRéthoré,KaterinaE.Aifantis,Concentration-GradientPrussianBlueCathodesforNa-IonBatteries.ACSEnergyLett.2020,5,100−108.[12]JinwenYin,Y.S.,ChangLi,ChenyangFan,ShixiongSun,YiLiu,JianPeng,LiQing,andJiantaoHan,InSituSelf-AssemblyofCore–ShellMultimetalPrussianBlueAnaloguesforHigh-PerformanceSodium-IonBatteries.ChemSusChem2019,12,4786–4790.[13]WenhaoRen,M.Q.,ZixuanZhu,MengyuYan,QiLi,LeiZhang,DongnaLiu,LiqiangMai,ActivationofSodiumStorageSitesinPrussianBlueAnaloguesviaSurfaceEtching.NanoLett.2017,17,4713−4718.[14]LingboRen,J.-G.W.,HuanyanLiu,MinhuaShao,BingqingWei,Metal-organic-framework-derivedhollowpolyhedronsofprussianblueanaloguesforhighpowergrid-scaleenergystorage.ElectrochimicaActa2019,321,134671.[15]DezhiYang,J.X.,Xiao-ZhenLiao,HongWang,Yu-ShiHe,Zi-FengMa,Prussianbluewithoutcoordinatedwaterasasuperiorcathodeforsodium-ionbatteries.Chem. Commun.2015,51,8181.[16]YangTang,W.Z.,LihongXue,XuliDing,TingWang,XiaoxiaoLiu,JingLiu,XiaochengLi,YunhuiHuang,Polypyrrole-promotedsuperiorcyclabilityandratecapabilityofNaxFe[Fe(CN)6]cathodesforsodiumionbatteries.J. Mater.Chem.A2016,4,6036.[17]KeLu,B.S.,YuxinZhang,HouyiMa,JintaoZhang,Encapsulationofzinchexacyanoferratenanocubeswithmanganeseoxidenanosheetsforhighperformancerechargeablezincionbatteries.J. Mater.Chem. A2017,5,23628.[18]DapengZhang,Z.Y.,JunshuZhang,HongzhiMao,JianYang,YitaiQian,Truncatedcobalthexacyanoferratenanocubesthreadedbycarbonnanotubesasahigh-capacityandhigh-ratecathodematerialfordual-ionrechargableaqueousbatteries.JournalofPowerSources2018,399,1-7.[19]QiYang,F.M.,ZhuoxinLiu,LongtaoMa,XinliangLi,DaliangFang,ShimouChen,SuojiangZhang,andChunyiZhi,ActivatingC-CoordinatedIronofIronHexacyanoferrateforZnHybrid-IonBatterieswith10000-CycleLifespanandSuperiorRateCapability.Adv. Mater.2019,31,1901521.[20]KosukeNakamoto,R.S.,YukiSawada,MasatoIto,andShigetoOkada,Over2VAqueousSodium-IonBatterywithPrussianBlue-TypeElectrodes.SmallMethods2019,3 (1800220).[21]XianyongWu,†YunkaiXu,§,†ChongZhang,†DanielP.Leonard,†AaronMarkir,†JunLu,*,‡andXiuleiJi,ReverseDual-IonBatteryviaaZnCl2Water-in-SaltElectrolyte.J. Am.Chem.Soc.2019,141,6338−6344.[22]XianyongWu,J.J.H.,WoochulShin,LuMa,TongchaoLiu,XuanxuanBi,YifeiYuan,YitongQi,T.WesleySurta,WenxiHuang,JoergNeuefeind,TianpinWu,P.AlexGreaney,JunLu,XiuleiJi Diffusion-freeGrotthusstopochemistryforhigh-rateandlong-lifeprotonbatteries.NatureEnergy2019,4,123–130.本文由作者团队供稿。

Li等[10]报道，首条Fe在Na1.60Mn0.833Fe0.167[Fe(CN)6]中掺杂，可降低Mn溶出和充放电过程中的结构应力 ，提高晶体热力学稳定性，因此表现出高的循环稳定性。特别的，电气P离子与-C≡N-中的N配位，R离子与-C≡N-中的C配位组成三维框架结构。

未来的储能器件需要较高工作电压、范线较高容量、较好的循环稳定性和倍率。

为了达到该目标，建成需要进一步开发PBAs性能优化方法。（b）扫描电镜照片（SEM）、中国（c）球差校正的扫描透射电镜照片（ADF-STEM）和（d）能量色散X-射线光谱(EDS)面扫图片。

制备纳米材料常用的合成方法有传统的水热和煅烧，首条这些方法是基于热辐射原理的块体加热过程，首条与传统的加热方法不同，非热辐射加热方法具有局部加热的特点。本文通讯作者：电气贾进，济南大学前沿交叉科学研究院讲师。

4.激光加热可以用来实现图案化制备，范线可以实现电极的一体化构建。建成图5.1 （a）激光在商业聚酰亚胺薄膜上制备图案化石墨烯示意图。